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Similar to Fe (VIII)O 4, Ir (IX)NO 3 has been predicted to be mildly metastable with respect to (η 2-NO)IrO 2 and (η 1-NO)IrO 2 but elimination of NO is predicted to be protected by considerable barriers thus leaving some hope that Ir (IX)NO 3 might be observed experimentally. Moving to the right in the periodic table, in group 9, only the observed + cation and the recently predicted neutral molecule IrNO 3 (nitride trioxide) feature genuine nonavalent transition metal center. The well-known group 8 complexes are represented by stable yet largely covalent Os (VIII)O 4 and the less stable and highly reactive Ru (VIII)O 4 while related Fe (VIII)O 4 has never been observed but it has been predicted to be metastable. The theoretical prediction and experimental observation of Ir (XI) oxidation state have raised the questions of kinetic and thermochemical stabilities of transition metal systems with uncommonly high oxidation numbers of a metal (coinciding with the group number). In other words, substantial covalence is often taken as an indication of strength of the chemical bonding. A similar trend may be noticed for many other homo- and related heteronuclear systems, with some interesting exceptions. If one now performs “electronegativity perturbation” by substituting one C atom by less electronegative B and another C atom by more electronegative N, the bonding energy is still high (389 kJ/mol), but it markedly decreases as compared with C 2. Take C 2 molecule, with the dissociation energy of 607 kJ/mol. Obviously, in this simplified picture, the homonuclear diatomics best fulfil the criteria which favour strong bonding, albeit heteronuclear systems may still benefit to a certain degree from an increased Coulombic stabilization, i.e. The better the match of energy and spatial distribution of orbitals (overlap), the stronger the chemical bond. spatial decay of electronic density) of atomic orbitals involved in chemical bonding. The classical theory of 2-electron/2-center chemical bonding based on a molecular orbital picture, as taught to the chemistry students, puts accent on proper match of energy and “size” (i.e. The analysis of a broader set of compounds containing group 8 and 9 metals in high formal oxidation states that correspond to the group number showed that, in contrast to a standard trend, the limits of formally attainable oxidation state correlate with high level of covalent bonding character in the complexes studied. However, the local minima containing Rh(IX) are protected by sufficient energy barriers on the decomposition pathway, and they could in principle be prepared. We found that both species studied are metastable with respect to elimination of O 2 or NO. Possible rearrangement into isomers featuring lower formal oxidation numbers has been explored. In this report, the stability and decomposition pathways of two species containing rhodium at a potentially formal +IX oxidation state, + and RhNO 3, have been investigated theoretically within the framework of the relativistic two-component Hamiltonian calculations. Rhodium, a 4d transition metal and a lighter analogue of iridium, is known to exhibit its highest VIth oxidation state in RhF 6 molecule. Now you can verify that if it syncs iCloud contacts with Outlook. Select Office 365 / and add the source.You can follow the instructions provided to generate an app-specific password. Select Apple iCloud and sign in to it.If you don’t trust such a third-party service, then you can skip this method. If you use SyncGene, you will need to let it access your info. If you are looking for a quick way to sync your iCloud contacts with Outlook, some third-party synchronization services that can help you with your need. Use SyncGene to sync iCloud contacts with Outlook for Mac and Windows Select a duplicate contact and choose a solution. It’ll found duplicate contacts in seconds and list them clearly. Go to the main window and select iCloud/Exchange in the sidebar. Cisdem Duplicate allows you to find and remove/merge duplicates efficiently. Is annoyed to locate a particular contacts from cluttered address book. There’s a possibility that lots of duplicate contacts appear after you finish sync. Tip: Remove or merge duplicate contacts after syncing Similarly, you can drag Exchange contacts into iCloud. Now you should be able to find your iCloud contacts in Outlook for Mac. Select iCloud in the sidebar and mass select all iCloud contacts.Now you should find iCloud and Exchange in the sidebar. Click the button next to the Updated contacts detected message.Click the plus icon + in the bottom left corner of the Internet Account window and choose Exchange.When you open it for the first time, click OK to grant access.If you have set up Outlook with your account and contacts can sync between the two, then you can use Cisdem ContactsMate, the best contact management app for Mac, to make things easier. Sync iCloud contacts with Outlook for Mac using ContactsMate Click the gear icon and choose Import vCard.Send the contacts to yourself as email attachments.Right-click and choose Forward as vCard.In the Navigation Bar of your Outlook app, click People.Part 2: Import Outlook contacts to iCloud The wizard will guide you through the process. In Outlook for Microsoft 365, Outlook 2019 or Outlook 2016 etc., choose File and go to Open & Export > Import/Export. Note: When it comes to Windows, the first four steps are the same. Now you can see and use them in the Outlook address book. This is how to import iCloud contacts to Outlook for Mac. vcf filename extension) and select Open With > Microsoft Outlook. Control-click the exported file (with the.Click the icon again and choose Export vCard.Click the gear icon in the bottom left corner and choose Select All.On your web browser, sign in to iCloud.Part 1: Import iCloud contacts to Outlook We will use Outlook for Mac as an example of how to use this method to sync iCloud contacts with Outlook for Mac and Windows. But you can do it manually, which is, fortunately, easy to do. The fact is that Outlook for Mac doesn’t officially support contact synchronization with iCloud. The Outlook app is available for Windows, Mac and mobile. Manually sync iCloud contacts with Outlook Let you backup/restore contacts with a click.Find and delete/merge duplicate contacts.Let you easily view, search, edit, group, tag, share, print and sync contacts.
(New) Exportable/importable preferences. Video track motion (picture-in-picture).Adjustable Velocity envelopes (-100 to 1000%).HDR video scopes: WFM / vector / parade / histogram.Support for multilayer Adobe Photoshop PSD files.Simultaneous video monitoring (local and external monitor).Project-wide video resample mode setting.(New) Tracking information for position-aware OFX plug-ins.(New) Combined RGB display for RGB parade video scope.(New) Adjustable vectorscope skin tone line.(New) Support for full range colors in 8-bit projects.(New) Metadata-based selection of HDR IDTs.(New) Artificial intelligence tools: Style Transfer and Colorization.Configurable timeline clip event headers.Customizable UI (button and window layouts, background color, and more).DVD and Blu-ray disc burning from the timeline.(New) Sound Forge Pro 14 multichannel audio editing.Boris FX Continuum Image Restoration Unit.Other new, improved, and existing advanced features include up to 8K resolution support, video noise reduction, a flicker filter, an improved color grading toolset, HDR video support, metadata-based selection of HDR IDTs, video stabilization, planar motion tracking, adjustable vectorscope skin tone line, multicamera audio synchronization, picture-in-picture motion tracking, screen capture, LUT export, 390+ video effects, 200+ transitions, and so much more. Colorization similarly lets you work with dropdowns and adjustment bars to visibly change the colors of objects or sections of your footage. Examples include the Japanese woodblock print, The Great Wave off Kanagawa. This is done by simply selecting one of these masterpieces from a dropdown. With Style Transfer, you can apply the visual styles of famous paintings and other works of art to your video footage. New features include Style Transfer and Colorization AI tools. Also, in line with the VEGAS legacy, VEGAS Pro 18 offers an open timeline that allows you to mix and match a wide variety of video and audio formats without transcoding them. You can import dialog, sound effects, and music into Sound Forge, use tools such as noise removal, metering, and visualization, and then export a final mix right back into your VEGAS Pro timeline in a seamless and efficient round trip. Yet, in addition to these tools, the included Sound Forge Pro 14 allows for a fully-comprehensive multichannel audio editing workflow. VEGAS has always stood out for providing many audio features, and that still applies. VEGAS Pro 18 is a Windows-compatible nonlinear editing software with vast sets of video and audio editing features. Please see the full list in the Features section below. The MAGIX VEGAS Pro 18 Suite packs VEGAS with Sound Forge Pro 14 and several third-party effects and transitions plug-ins, including ActionVFX Action Pack, Boris FX Film Style Unit, and NewBlue Transitions 5 Ultimate. Experience a much more varied pool of random events every year, as well as specific heart-wrenching (or heart-stabbing!) reactive content for when you, as an example, lie dying, or when someone close to you takes part in a foreign battle. Over one hundred new events and event chains which expand upon the relationships you have with your family, friends, rivals, best friends, and nemeses.Thanks for reading and playing, and remember: an enemy is just another potential lover that is slightly harder to woo! Below you can find what you were actually looking for in this thread. Jokes and tidbits aside it has been super fun working on Friends & Foes, I could absolutely not have done it without the rest of the team and I hope you all enjoy it. The gallows art is very well done, but also weirdly "upbeat" according to the design team.We added a new jungle event image that had so many hidden monkeys that we kept finding new ones throughout the dev cycle, we probably haven't found them all yet.Doing the merge itself was also a lot of fun, I'll be releasing a book about it titled "Zack and the Merge That Never Ended" and I'm forcing the design team ( who no doubt made fun of me during the ordeal ) to write it for me, good luck. We had a merge that got screwed up so bad that it broke our changelog generation, therefore I had to manually find a lot of entries ( needle, haystack, fun ).Then when I realized I had to fix it I didn't find it funny anymore but then QA suddenly thought it was funny, so I guess it evened out. We had a technical issue that only happened when saving saves with an even number of characters, it worked with an odd number.The '&' in Friends & Foes caused technical issues in one specific backend system due to it being a special character, so it had to be redone.but I wasn't here then so Joel had to do it for me instead ( funny ).It was probably the winner anyway, right? We collected a bunch of name suggestions for the update and voted but I forgot which one we decided on and just picked "Bastion" because that was my favorite."Fun" tidbits from the development of F&F: Slack stays within the scope of team chat which makes for a clean, intuitive interface. Channels are “ dedicated spaces” for conversations to take place according to subject matter, team, etc. Connect with your colleagues, in real time, in three ways: direct messages, voice and video calls, and channels. Best free team chat apps - with limited benefits! SlackĪs a team communication app, Slack strikes a balance between functionality and simplicity. Microsoft Teams is free! However, if you’d like Microsoft 365 (which includes Microsoft Teams), pricing starts at $5/user per month. Packed with features and productivity app integrations, Microsoft Teams makes it easy to connect and collaborate with your colleagues - even within a free personal plan. It includes 1:1 and group chats, video calls (which you can launch straight from your chat window), file sharing, and more. Microsoft Teamsįor teams who are already using Microsoft 365, Microsoft Teams is a natural choice for easing communication along. Google Workspace starts at $6/user per month for the Business Starter plan. Google Chat is free for personal plans and comes with limited features. Then of course, you have Meet, which is Google’s video conferencing tool. Rooms behave similarly to channels in Slack in that they’re intended to provide a home for long-term collaboration around specific teams or projects - as opposed to one-off messages. Chat covers your basic 1:1 and group instant messaging. While Google Chat used to be only available with Google Workspace accounts, it’s now available in your free personal accounts.Ĭommunication takes place in three places: Chat, Rooms, and Meet. Google Chat, previously known as Hangouts Chat, is a standout choice if you want core communication features in a clean interface. For a more comprehensive breakdown of what each app has to offer (as well as the most up-to-date pricing), visit the appropriate websites - links are below! Best free team chat apps Google Chat Note: This article is only meant to narrow down your choices and point you in the right direction. Think about what problems you’re looking to solve and how you and your team members like to work, keeping in mind that many companies offer free trials so you can always give it a spin before you commit. Other chat apps keep it simple by doing one thing and doing it really well - perfect for those who prefer to keep instant messaging separate from their other activities. These tools are ideal for people who prefer not to have their work scattered across multiple apps. Some apps make it easy to work out of a single platform by combining team chat with video conferencing, project management, cloud storage, and more. If you want to optimize your team’s communication (which will in turn, optimize every other aspect of your work), keep reading for the best team communication apps in 2022. But with new apps and tools popping up nearly every day, how do you cut through the noise and pick the right one? The modern team demands it, whether you’re a team of two or two-thousand - especially since the rise in remote and distributed work. Long gone are the days when a team messaging app was nice to have. And a fully colored and detailed background location with foreground animation goes with the art direction and production design credit.ġ8. A loop of dogs runs to honor the character animators, letters twinkle in the names of the effects animators, Pongo and Perdita appear on a city street for the names of the layout technicians, color washes across the background for the names of the color stylist and background artists. A quick animation of Pongo’s head accompanies the names of the directing animators. Dalmatian spots form musical notes during the credit for the film’s music. In the final moments of The Wump World, the Wumps emerge from their hiding places and wander lost among the abandoned and inhospitable concrete wasteland, until they joyfully happen upon one last unspoiled remnant of their planet.ġ7. The Wump World follows an innocent society of capybara-like animals called Wumps, whose home is colonized into ruin by wasteful alien invaders who get back in their rocketships and find another planet to despoil the moment they have exhausted all the resources.ġ1. He went on to be a successful writer and illustrator of children’s books, including The Wump World.ġ0. Peet did quit just a few years after One Hundred and One Dalmatians came out, after arguing with Walt during the production of The Jungle Book. Peet nearly quit before he was promoted to the story department in time to work on Pinocchio.ĩ. Peet cut his teeth at Disney animation doing menial animation work on Donald Duck shorts.Ĩ. One Hundred and One Dalmatians was the first Disney animated feature to be written and storyboarded by one person, animator and writer Bill Peet.ħ. It also set the visual style of Disney animation (a scratchy, hard outline look) for years until the technology advanced enough (with the production of Rescuers, The (1977)) to allow a softer look.6. The first Disney feature film to use photocopying technology (Xerography), which made an animated film with this much visual complexity possible. This was the media event of the year in 1952. This helps us to date the story, since the Carlsen in question is Kurt Carlsen, captain of the freighter Flying Enterprise, which sank after a prolonged struggle in the Atlantic. The only headline on the front page (apart from the dognapping) is CARLSEN SPEAKS, and a picture of a capsized ship. When the Baduns are talking on the phone to Cruella, they are holding a newspaper. Several of the characters from Lady and the Tramp (1955) can be seen in a pet shop window during the twilight bark sequence.Īt one point Jasper and Horace's TV set features Disney's award-winning cartoon short Flowers and Trees (1932). Someone counted all black spots in the movie, frame-by-frame, and reached the total of 6,469,952. Jeanette sons Thomas, Doug and Gregg daughter Ann The art of animation, most notably DisneyĪnimation: The Illusion of Life (Hyperian Press,ġ978) and The Disney Villain (Hyperion Press,ġ993). Johnston, they went on to author many fine books about Longtime friend, and fellow Disney collaborator Ollie Near 44-year relationship with the studio. Thomas retired from Disney in early 1978, ending a Of Bernard and Bianca in the underrated The In The Jungle Book (1967) and his final work Sleeping Beauty (1959) Baloo, Mowgli and Kaa Love over a dish of spaghetti and meatballs in LadyĪnd the Tramp (1955) the three good fairies in Peter Pan (1953) the Lady and Rover falling in Sequence between Captain Hook and Peter Pan in Skate in Bambi (1941) the wicked stepmother inĬinderella (1950), the Queen of Hearts inĪlice in Wonderland (1951), the terrific fight In Pinocchio, (1940) Thumper teaching Bambi to Justly cherished the world over: the title character Of the high watermarks in Disney animation that is Thomas' work from this point on would be nothing short Had never experienced before, and his career was set. Humorous detail to animated characters that audiences The seven dwarfs offered an emotional sweep and The key animators for the studios' first,įeature-length animated picture, Snow White and the Short Mickey's Elephant in 1936, and was one of Soon after, he began work for Waltĭisney Studios and did his first animation for the Graduated from Stanford University in 1934 with aĭegree in art. He showed an interest in art and drawingĪt a very young age, so it came as no surprise when he He had been inĭeclining health since suffering a brain hemorrhageĬalifornia. Hits like The Rescuers, died on September 8 in The Seven Dwarfs to equally acclaimed modern Ranged from such '30s classics like Snow White and Legendary Disney animator Frank Thomas, whose work El ō s, which stands for Electro-Optical Synergy, combines optical power and radiofrequency energy for enhanced penetration to layers and tissues underneath the skin. Just when you thought you’d seen all that cosmetic lasers and medical lasers can do, Syneron Lasers then made their debut with the revolutionary el ō s technology. Air Cooling Compatible (ACC): This device promotes patient comfort by directing cold air to the treatment area.Hone The Dual Power of Electro-Optical Synergy with Syneron Lasers.Dynamic Cooling Device (DCD): As the name implies, it delivers consistent bursts of protective cryogen at the treatment area to avoid burns and overtreatment.Lens-coupled optical fiber with handpieceġ07 cm H x 46 cm W x 69 cm D (42” x 18” x 27”)Ģ00-240 VAC, 50/60 Hz, 30A, 4600 VA single phaseĬandela GentleMax Pro features two handpieces that are designed for skin protection and patient comfort: Λ2 Specialty Delivery System Option Spot Sizes The treatment can take 30 minutes to 1 hour, depending on the existing skin condition, treated area, and desired cosmetic goals. A tolerable stinging sensation is normal and is a desired clinical outcome as the therapeutic heat is being absorbed by the skin tissue. A pulse of laser light will then be emitted in order to target hair follicles or simulate skin cell renewal. What Happens during a Candela GentleMax Pro Treatment?Ĭandela GentleMax Pro will first emit a pulse of cooling spray in the treatment area to protect it against burn and improve comfort. In addition, its Air Cooling Compatible (ACC) technology improves patient comfort by directing cold air into the area. This is because Candela GentleMax Pro’s patented Dynamic Cooling Device (DCD) technology allows it to deliver consistent bursts of protective cryogen (a substance that produces very low temperature) while preventing thermal damage in the treatment area. The treatment is safe and effective for all skin types. Vascular lesions (flat or raised lesions).Telangiectasia (threadlike red lines on skin).Pseudofoliculitis barbae (shaving bumps).What Conditions can Candela GentleMax Pro Treat?Ĭandela GentleMax Pro’s dual wavelength allows practitioners to treat a myriad of indications such as the following: This process replaces old skin cells with new, healthy skin cells, resulting in healthier, radiant, and younger-looking skin. For skin rejuvenation treatments, the Candela GentleMax Pro’s laser energy stimulates the production of collagen, resulting in skin cell renewal. This in turn produces adequate amount of heat energy and destroys the hair follicle, resulting in permanent hair removal. The Candela GentleMax Pro’s laser beam passes through the deeper layer of the skin and is absorbed in the hair follicle. The system combines the power of 755 nm Alexandrite laser with 1064 nm Nd:YAG laser to provide safe, comfortable, quick, and effective cosmetic solution to a wide array of skin conditions with a single beam of laser light. Its dual wavelength allows practitioners to treat a multitude of skin concerns with no downtime. The Candela GentleMax Pro is a game changer in the field of high-speed laser hair removal and skin rejuvenation. Manufacture Ī wallboard panel consists of a layer of gypsum plaster sandwiched between two layers of paper. The European Commission imposed fines totaling €420 million on the companies Lafarge, BPB, Knauf and Gyproc Benelux, which had operated a cartel on the market which affected 80% of consumers in France, the UK, Germany and the Benelux countries. Vertically hung drywall with joint compound In 1936, US Gypsum trademarked ROCKLATH for their gypsum lath product. As it evolved, it was faced with paper impregnated with gypsum crystals that bonded with the applied facing layer of plaster. An alternative to traditional wood or metal lath was a panel made up of compressed gypsum plaster board that was sometimes grooved or punched with holes to allow wet plaster to key into its surface. Gypsum lath was an early substrate for plaster. Later air entrainment technology made boards lighter and less brittle, and joint treatment materials and systems also evolved. Providing installation efficiency, it was developed additionally as a measure of fire resistance. In 1910 United States Gypsum Corporation bought Sackett Plaster Board Company and by 1917 introduced Sheetrock. Gypsum board evolved between 19, beginning with wrapped board edges and the elimination of the two inner layers of felt paper in favor of paper-based facings. Sheets were 36 by 36 by 1⁄ 4 inch (914 mm × 914 mm × 6 mm) thick with open (untaped) edges. It was made by layering plaster within four plies of wool felt paper. Sackett Board was invented in 1894 by Augustine Sackett and Fred Kane, graduates of Rensselaer Polytechnic Institute. The first plasterboard plant in the UK was opened in 1888 in Rochester, Kent. In the mid-20th century, drywall construction became prevalent in North America as a time- and labor-saving alternative to lath and plaster. The plaster is mixed with fiber (typically paper, glass wool, or a combination of these materials) plasticizer, foaming agent and additives that can reduce mildew, flammability, and water absorption. Panel made of gypsum, used in interior construction Various sized cuts of 1⁄ 2 in (13 mm) drywall with tools for maintenance and installationĭrywall (also called plasterboard, dry lining, wallboard, sheet rock, gib board, gypsum board, buster board, turtles board, slap board, custard board, and gypsum panel) is a panel made of calcium sulfate dihydrate ( gypsum), with or without additives, typically extruded between thick sheets of facer and backer paper, used in the construction of interior walls and ceilings. Certain features require specific hardware (see Windows 11 Specifications).Ĭertain features require specific hardware, see Windows 11 Specifications. Features and app availability may vary by region. Windows 11 upgrade is available for eligible PCs that meet minimum device specifications. Requires an NVMe SSD to store and run games that use the Standard NVM Express Controller driver and a DirectX12 GPU with Shader Model 6.0 support.įor computers with Windows 10 in S mode, download this version of PC Health Check app. See and and for details.Īuto HDR requires an HDR monitor and is supported on titles using the DirectX 11 or later API.ĭirectStorage requires API adoption by games. Requires Windows 10/11 (with updates) excludes S mode and ARM devices. Game catalog varies over time, by region, and by device. PCs that have been running previous versions of Windows must do a full reset of the Windows 11 operating system for the feature to work. In order to keep you as safe as possible, you must start with a fresh system. Only available on the latest version of Windows 11. Some layouts only available based on display resolution and scale settings.ĭuring the device support period provided by the Original Equipment Manufacturer (OEM). Narrator natural voices availability varies by market: See Appendix A: Supported languages and voices. US English only for live captions, and voice access. Requires Windows PC with microphone capability. |
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